2023
Development of Catalysts for Increasing Soybean Oil Content in Renewable Coatings
Contributor/Checkoff:
Category:
Industrial
Keywords:
CoatingsOil
Parent Project:
This is the first year of this project.
Lead Principal Investigator:
Alexander Parent, North Dakota State University
Co-Principal Investigators:
Project Code:
NDSC 2023 NewUse 6
Contributing Organization (Checkoff):
Institution Funded:
Brief Project Summary:
Soybean oil is a component of many renewable and bio-based coating formulations; however the actual amount is typically only between 5-30% of the overall components. This research will enable the incorporation of greater soybean oil percentages into these renewable coating formulations. This could increase demand for soybean oil for this established, high-volume, high-value market. This research is also expected to lead to soybean oil-based coatings with improved physical and chemical properties, which will allow the use of these coatings in applications currently reserved for petroleum-based formulations.
Key Beneficiaries:
#chemists, #engineers, #farmers, #scientists
Unique Keywords:
#bio-based, #catalysis, #chemistry, #coatings, #driers, #new uses, #soybean oil
Information And Results
Project Summary

Air-drying coatings typically contain three major components: a binder that forms the final coating, a solvent that affects coating consistency and ease of application, and a drier that enhances the rate at which the binder converts into the final coating. Historically, drying oils such as soybean oil have been used as binders in coatings, but these natural binders were displaced by petroleum-based binders in the 20th century. Recent interest in more renewable and less toxic coatings has led to renewed interest in drying oils as binders, leading to the commercialization of several soybean oil-based coatings. Unfortunately, these coatings typically only contain a small fraction of “renewable” i.e., soybean oil-derived, binder with the bulk still derived from petroleum. This is because petroleum-derived binders dry much faster than soybean oil, limiting the amount of soybean oil that can be added before drying times become unacceptably long. This limitation is a consequence of using soybean oil as a drop-in replacement in coatings using driers optimized for petroleum-derived binders. In order to address this limitation, driers specifically designed for use with soybean oil must be developed. Specifically, more active driers are needed to compensate for the longer intrinsic drying time of soybean oil. Our group has been researching the mechanisms by which driers catalyze the air-drying of drying oils as part of the NDSU Center for Sustainable Materials Science (CSMS). The proposed research will apply the insights from our CSMS research to develop superior driers for soybean oil-based coatings.

Project Objectives

1. Measure the drying ability of commercial cobalt and iron-based driers with soybean oil.
2. Characterize the structural properties of cobalt and iron-based driers that enhance the properties of soybean oil-based coatings.
3. Design cobalt and iron-based driers optimized for use with soybean oil.

Project Deliverables

1. Optimal reaction parameters for forming renewable coatings from soybean oil.
2. New driers for use with soybean oil and soybean oil containing coating formulations.
3. Soybean oil coating formulations with superior drying times and material properties.

Progress Of Work
Final Project Results

Benefit To Soybean Farmers

Soybean oil is already used as a component of many renewable and bio-based coating formulations, however the actual amount of soybean oil used in these formulations is typically only between 5-30% of the overall organic components. This research will enable the incorporation of greater percentages of soybean oil into these renewable coating formulations, increasing the demand for soybean oil for this established, high-volume, high-value market. This research is also expected to lead to soybean oil-based coatings with improved physical and chemical properties, which will allow the use of these coatings in more demanding applications currently reserved for petroleum-based formulations. Because of the size of the coatings sector (estimated at 40 million metric tons in 2020), even a small increase in the amount of soybean oil used in this sector is expected to increase the overall value of soybean oil, in turn enhancing the value of the soy crop to ND farmers.

The United Soybean Research Retention policy will display final reports with the project once completed but working files will be purged after three years. And financial information after seven years. All pertinent information is in the final report or if you want more information, please contact the project lead at your state soybean organization or principal investigator listed on the project.