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The objective of this project was to evaluate the potential of modified soybean oils (SBO) as additives for poly(styrene-butadiene) (SBR) rubber compounds for reduction of coefficient of surface friction of the rubber. SBR rubber is widely used for the manufacturing of conveyor belts and rubber belts for various agriculture harvesting equipment. SBR rubber has good mechanical strength and durability but has a high coefficient of friction (COF) which leads to overheating and damaging of the rubber belt. Chemically modified soybean oils were studied as additives to SBR rubber compounds. The compounds were vulcanized and tested for surface friction after different periods of time. Two modified SBOs were selected as additives that reduce surface friction. One additive is partially hydrogenated soybean oil (PHSO) which is an inexpensive commercial product having wide application in the food industry, cosmetics, and household products. The second additive named SOFA was synthesized by chemical modification of SBO with polystyrene and a fluoroacrylate. Both modified SBOs demonstrated reduction of surface friction of rubber compared to the reference rubber (see figure).
The SBR compounds were formulated with carbon black, petroleum-based aromatic oil, and different amounts of the modified soy-based additives. For some compounds, the petroleum-based oil was completely replaced with soy-based additives. Compounds were vulcanized and tested for mechanical properties. The results demonstrated that PHSO improves the mechanical properties of rubber such as tensile strength and hardness. SOFA slightly reduces the tensile strength of rubber but provides a stable reduction of surface friction. Both PHSO and SOFA can be used as additives for SBR compounds with enhanced mechanical and improved surface properties.
This project has identified a new potential use for soybean oil in industrial applications: for the modification of the surface friction properties of rubber compounds.